Hi, i had that problem last week (I made a post when it happened). Until today, after a reboot, all was working correctly as I tested it on several computers.
Today, I checked back my specs on my main computer (the one that "cannot initialize cpu dll") and the problem poped back again.
It says "cannot initialise spc dll" now. Here is a picture of what i'm talking about:
I use Windows XP pro SP3, with the portable version of Speccy v1.11 (I tried my v1.10 installed version WITHOUT rebooting and the same error messages appeared).
As I thought, when I rebooted, it worked correctly on both version. Anyone knows why it needs a reboot?